ORIGINAL
原著論文
Original Paper
2024
- Weak Base-Promoted Direct Cross-Coupling of Naphthalene-1,8-diaminato-Substituted Arylboron Compounds
K. Tomota, J. Li, H. Tanaka, M. Nakamoto, T. Tsushima, H. Yoshida
JACS Au 2024, 4, 3931–3941.
DOI: 10.1021/jacsau.4c00665 - Surefire generation of stannylpotassium: highly reactive stannyl anions and applications
Y. Hiraoka, T. Imagawa, K. Nakanishi, H. Kawabe, M. Nakamoto, T. Tsushima, H. Yoshida
Chem. Sci. 2024, 15, 15152–15159.
DOI: 10.1039/D4SC04526B - Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes
T. Tsushima, M. Nakamoto, H. Yoshida
ACS Catal. 2024, 14, 12694–12703.
DOI: 10.1021/acscatal.4c04451 - Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
S. Kamio, M. Nakamoto, T. Yamagishi, M. Oestreich, H. Yoshida
Chem. Commun. 2024, 60, 6379–6382. (CC 60th Anniversary Authors Collections)
DOI: 10.1039/D4CC01005A - Ethynyl–B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron-Containing Heteroaromatic Compounds
J. Li, H. Tanaka, T. Imagawa, T. Tsushima, M. Nakamoto, J. Tan, H. Yoshida
Chem. Eur. J. 2024, 30, e202303403.
DOI: 10.1002/chem.202303403
2023
- Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines
Y. Guo, Z. Zhuang, X. Feng, Q. Ma, N. Li, C. Jin, H. Yoshida, J. Tan
Org. Lett. 2023, 25, 7192–7197.
DOI: 10.1021/acs.orglett.3c02785 - Complexation-Triggered Fluctuation of π-Conjugation on an Antiaromatic Dicyanoanthracene Dianion
T. Imagawa, K. Okazawa, K. Yoshizawa, H. Yoshida, R. Shang, Y. Yamamoto, M.Nakamoto,
Chem. Eur. J. 2023, 29, e202302550.
DOI: 10.1002/chem.202302550 - Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds
K. Tomota, Y. Izumi, K. Nakanishi, M. Nakamoto, H. Yoshida
Org. Biomol. Chem. 2023, 21, 5347–5350. (Highlighted as a Front Cover Picture)
DOI: 10.1039/D3OB00613A - Direct Suzuki–Miyaura Coupling of Naphthelene-1,8-diaminato (dan)-Substituted Cyclopropylboron Compounds
M. Koishi, K. Tomota, M. Nakamoto, H. Yoshida
Adv. Synth. Catal. 2023, 365, 682–686. (Highlighted as a Front Cover Picture)
DOI: 10.1002/adsc.202201141 - Stable Silapyramidanes
T. Imagawa, L. Giarrana, D. M. Andrada, B. Morgenstern, M. Nakamoto, D. Scheschkewitz
J. Am. Chem. Soc. 2023, 145, 4757–4764.
DOI: 10.1021/jacs.2c13530 - Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides
H. Tanaka, M. Nakamoto, H. Yoshida
RSC Adv. 2023, 13, 2451–2457.
DOI: 10.1039/D2RA07826K
2022
- A stable silylborane with diminished boron-Lewis acidity
H. Yoshida, Y. Izumi, Y. Hiraoka, K. Nakanishi, M. Nakamoto, S. Hatano, M. Abe
Dalton Trans. 2022, 51, 6543–6546.
DOI: 10.1039/D2DT00962E - Platinum–P(BFPy)3-catalyzed regioselective diboration of terminal alkynes with (pin)B–B(aam)
I. Kageyuki, J. Li, H. Yoshida
Org. Chem. Front. 2022, 9, 1370–1374.
DOI: 10.1039/D1QO01903A
2021
- Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes
T. Tsushima, H. Tanaka, K. Nakanishi, M. Nakamoto, H. Yoshida
ACS Catal. 2021, 11, 14381–14387.
DOI: 10.1021/acscatal.1c04244 - HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
S. Kamio, T. Imagawa, M. Nakamoto, M. Oestreich, H. Yoshida
Synthesis 2021, 53, 4678–4681.
DOI: 10.1055/a-1558-9135 - Synthesis and Isolation of an Anionic Bis(dipyrido-annulated) N-Heterocyclic Carbene CCC-Pincer Iridium(III) Complex by Facile C–H Bond Activation
K. Nakanishi, J. O. C. Jimenez-Halla, S. Yamazoe, M. Nakamoto, R. Shang, Y. Yamamoto
Inorg. Chem. 2021, 60, 9970–9976.
DOI: 10.1021/acs.inorgchem.1c01236
2020
- Isolation and Computational Studies of a Digallane Gold Complex with a 12-Electron Auride Center
K. Susukida, L. Lugo-Fuentes, S. Matsumae, K. Nakanishi, M. Nakamoto, Y. Yamamoto, R. Shang, J. Barroso-Flores, J. O. C. Jimenez-Halla
Organometallics, 2020, in press
DOI: 10.1021/acs.organomet.0c00557 - Complexation of B(C6F5)3 and 9,10-Dicyanoanthracene: Dual Role of Borane as Spatial and Electronic Tuner
T. Imagawa, M. Nakamoto, R. Shang, Y. Adachi, J. Ohshita, N. Tsunoji, Y. Yamamoto
Chem. Lett. 2020, 49, 1022–1025. (Editor’s Choice)
DOI: 10.1246/cl.200339 - Transition Metal-Free B(dan)-Installing Reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) Electrophile
J. Li, M. Seki, S. Kamio, H. Yoshida
Chem. Commun. 2020, 56, 6388–6391.
DOI: 10.1039/D0CC02560G - Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons
H. Yoshida, M. Seki, S. Kamio, H. Tanaka, Y. Izumi, J. Li, I. Osaka, M. Abe, H. Andoh, T. Yajima, T. Tani, T. Tsuchimoto
ACS Catal. 2020, 10, 346–351.
DOI: 10.1021/acscatal.9b03666
2019
- One-pot Sequential Fluorostannylation–Arylstannylation of Arynes
H. Tanaka, I. Osaka, H. Yoshida
Chem. Lett. 2019, 48, 1032–1034. (Editor’s Choice)
DOI: 10.1246/cl.190385 - Copper-Catalyzed Arylstannylation of Arynes in a Sequence
H. Tanaka, H. Kuriki, T. Kubo, I. Osaka, H. Yoshida
Chem. Commun. 2019, 55, 6503–6506.
DOI: 10.1039/C9CC02738F - Anthranilamide-Substituted Borane [H–B(aam)]: Its Stability and Application to Iridium-Catalyzed Stereoselective Hydroboration of Alkynes
H. Yoshida, M. Kimura, H. Tanaka, Y. Murashige, I. Kageyuki, I. Osaka
Chem. Commun. 2019, 55, 5420–5422. (Highlighted in Front Cover)
DOI: 10.1039/C9CC02002K - Copper-Catalyzed B(dan)-Installing Allylic Borylation of Allylic Phosphates
H. Yoshida, Y. Murashige, I. Osaka
Adv. Synth. Catal. 2019, 361, 2286–2290.
DOI: 10.1002/adsc.201900342 - Anthranilamide (aam)-Substituted Arylboranes in Direct Carbon–Carbon Bond-Forming Reactions
S. Kamio, I. Kageyuki, I. Osaka, H. Yoshida
Chem. Commun. 2019, 55, 2624–2627.
DOI: 10.1039/C8CC10252J
2018
- Anthranilamide (aam)-Substituted Diboron: Palladium-Catalyzed Selective B(aam) Transfer
S. Kamio, I. Kageyuki, I. Osaka, S. Hatano, M. Abe, H. Yoshida
Chem. Commun. 2018, 54, 9290–9293.
DOI: 10.1039/C8CC05645E - Preparation of (pin)B–B(dan)
H. Yoshida, Y. Murashige, I. Osaka
Org. Synth. 2018, 95, 218–230.
DOI: 10.15227/orgsyn.095.0218 - Copper-Catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar–Br Bond
H. Yoshida, S. Kamio, I. Osaka
Chem. Lett. 2018, 47, 957–959.
DOI: 10.1246/cl.180385
REVIEW
総説
Review
2022
- ホウ素あるいはスズを含む有機典型金属化合物が拓く有機合成
吉田拡人
有機合成化学協会誌 2022, 80, 477–488.
DOI: 10.5059/yukigoseikyokaishi.80.477
2021
- Borylation and Stannylation Reactions with Tuning of Lewis Acidity
H. Yoshida
Chem. Rec. 2021, 21, 3483–3497.
DOI: 10.1002/tcr.202100099 - Recent Advances in Synthetic Transformations with Robust yet Reactive B(dan) Moiety
J. Li, H. Yoshida
Heterocycles 2021, 102, 1478–1516.
DOI: 10.3987/REV-20-949 - Synthetic Chemistry with Lewis Acidity-Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross-Coupling
S. Kamio, H. Yoshida
Adv. Synth. Catal. 2021, 363, 2310–2324. (Selected as VIP)
DOI: 10.1002/adsc.202001460
2020
- A Leap forward in Sulfonium Salt and Sulfur Ylide Chemistry
R. Fan, C. Tan, Y. Liu, Y. Wei, X. Zhao, X. Liu, J. Tan, H. Yoshida
Chin. Chem. Lett. 2021, 32, 299–312.
DOI: 10.1016/j.cclet.2020.06.003
BOOK
著書
Book
2022
- Product Subclass 6: Silyltin Reagents
H. Yoshida
In Science of Synthesis Knowledge Updates, Thieme,2022
DOI: 10.1055/sos-SD-104-00776 - Comprehensive Aryne Synthetic Chemistry
H. Yoshida (Editor)
Elsevier, 2022, pp. 1–380. - Insertion into σ-bonds
H. Tanaka, H. Yoshida
In Comprehensive Aryne Synthetic Chemistry, ed. by H. Yoshida, Elsevier, 2022, pp. 57–123.
2021
- 「アルケン，アルキンのボリル官能基化」「アラインの官能基化」
吉田 拡人
有機合成のための新触媒反応101, 有機合成化学協会編，東京化学同人 - Multicomponent Reactions Involving Arynes and Related Chemistry
H. Yoshida
In Modern Aryne Chemistry, ed. by A. T. Biju, Wiley-VCH, 2021, pp. 149–182. - N-(Carboxymethyl)-N-Methyl-Glycine
H. Yoshida
In e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley, 2021
DOI: 10.1002/047084289X.rn01228.pub2
2020
- 1H-Naphtho[1,8-de]-1,3,2-diazaborine, 2,3-Dihydro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
H. Yoshida
in e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley, 2020.
DOI: 10.1002/047084289X.rn02327 - Diboron Compounds: Synthesis and Applications
H. Yoshida
in Science of Synthesis Reference Library: Advances in Organoboron Chemistry toward Organic Synthesis, ed. by E. Fernández, Thieme, Stuttgart, 2020, pp. 31–82.
DOI: 10.1055/sos-SD-230-00018