Original Paper


  • Ethynyl–B(dan) in [3+2] Cycloaddition and Larock Indole Synthesis: Synthesis of Stable Boron-Containing Heteroaromatic Compounds
    J. Li, H. Tanaka, T. Imagawa, T. Tsushima, M. Nakamoto, J. Tan, H. Yoshida
    Chem. Eur. J. 2024, 30, e202303403.
    DOI: 10.1002/chem.202303403


  • Selective S-Arylation of Sulfenamides with Arynes: Access to Sulfilimines
    Y. Guo, Z. Zhuang, X. Feng, Q. Ma, N. Li, C. Jin, H. Yoshida, J. Tan
    Org. Lett. 2023, 25, 7192–7197.
    DOI: 10.1021/acs.orglett.3c02785
  • Complexation-Triggered Fluctuation of π-Conjugation on an Antiaromatic Dicyanoanthracene Dianion
    T. Imagawa, K. Okazawa, K. Yoshizawa, H. Yoshida, R. Shang, Y. Yamamoto, M.Nakamoto,
    Chem. Eur. J. 2023, 29, e202302550.
    DOI: 10.1002/chem.202302550
  • Efficient one-pot synthesis of dan-substituted organo- and silyl-boron compounds
    K. Tomota, Y. Izumi, K. Nakanishi, M. Nakamoto, H. Yoshida
    Org. Biomol. Chem. 2023, 21, 5347–5350. (Highlighted as a Front Cover Picture)
    DOI: 10.1039/D3OB00613A
  • Direct Suzuki–Miyaura Coupling of Naphthelene-1,8-diaminato (dan)-Substituted Cyclopropylboron Compounds
    M. Koishi, K. Tomota, M. Nakamoto, H. Yoshida
    Adv. Synth. Catal. 2023, 365, 682–686. (Highlighted as a Front Cover Picture)
    DOI: 10.1002/adsc.202201141
  • Stable Silapyramidanes
    T. Imagawa, L. Giarrana, D. M. Andrada, B. Morgenstern, M. Nakamoto, D. Scheschkewitz
    J. Am. Chem. Soc. 2023, 145, 4757–4764.
    DOI: 10.1021/jacs.2c13530
  • Computed ammonia affinity for evaluating Lewis acidity of organoboronates and organoboronamides
    H. Tanaka, M. Nakamoto, H. Yoshida
    RSC Adv. 2023, 13, 2451–2457.
    DOI: 10.1039/D2RA07826K


  • A stable silylborane with diminished boron-Lewis acidity
    H. Yoshida, Y. Izumi, Y. Hiraoka, K. Nakanishi, M. Nakamoto, S. Hatano, M. Abe
    Dalton Trans. 2022, 51, 6543–6546.
    DOI: 10.1039/D2DT00962E
  • Platinum–P(BFPy)3-catalyzed regioselective diboration of terminal alkynes with (pin)B–B(aam)
    I. Kageyuki, J. Li, H. Yoshida
    Org. Chem. Front. 2022, 9, 1370–1374.
    DOI: 10.1039/D1QO01903A


  • Origins of Internal Regioselectivity in Copper-Catalyzed Borylation of Terminal Alkynes
    T. Tsushima, H. Tanaka, K. Nakanishi, M. Nakamoto, H. Yoshida
    ACS Catal. 2021, 11, 14381–14387.
    DOI: 10.1021/acscatal.1c04244
  • HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters
    S. Kamio, T. Imagawa, M. Nakamoto, M. Oestreich, H. Yoshida
    Synthesis 2021, 53, 4678–4681.
    DOI: 10.1055/a-1558-9135
  • Synthesis and Isolation of an Anionic Bis(dipyrido-annulated) N-Heterocyclic Carbene CCC-Pincer Iridium(III) Complex by Facile C–H Bond Activation
    K. Nakanishi, J. O. C. Jimenez-Halla, S. Yamazoe, M. Nakamoto, R. Shang, Y. Yamamoto
    Inorg. Chem. 2021, 60, 9970–9976.
    DOI: 10.1021/acs.inorgchem.1c01236


  • Isolation and Computational Studies of a Digallane Gold Complex with a 12-Electron Auride Center
    K. Susukida, L. Lugo-Fuentes, S. Matsumae, K. Nakanishi, M. Nakamoto, Y. Yamamoto, R. Shang, J. Barroso-Flores, J. O. C. Jimenez-Halla
    Organometallics, 2020, in press
    DOI: 10.1021/acs.organomet.0c00557
  • Complexation of B(C6F5)3 and 9,10-Dicyanoanthracene: Dual Role of Borane as Spatial and Electronic Tuner
    T. Imagawa, M. Nakamoto, R. Shang, Y. Adachi, J. Ohshita, N. Tsunoji, Y. Yamamoto
    Chem. Lett. 2020, 49, 1022–1025. (Editor’s Choice)
    DOI: 10.1246/cl.200339
  • Transition Metal-Free B(dan)-Installing Reaction (dan: naphthalene-1,8-diaminato): H–B(dan) as a B(dan) Electrophile
    J. Li, M. Seki, S. Kamio, H. Yoshida
    Chem. Commun. 2020, 56, 6388–6391.
    DOI: 10.1039/D0CC02560G
  • Direct Suzuki–Miyaura Coupling with Naphthalene-1,8-diaminato (dan)-Substituted Organoborons
    H. Yoshida, M. Seki, S. Kamio, H. Tanaka, Y. Izumi, J. Li, I. Osaka, M. Abe, H. Andoh, T. Yajima, T. Tani, T. Tsuchimoto
    ACS Catal. 2020, 10, 346–351.
    DOI: 10.1021/acscatal.9b03666


  • One-pot Sequential Fluorostannylation–Arylstannylation of Arynes
    H. Tanaka, I. Osaka, H. Yoshida
    Chem. Lett. 2019, 48, 1032–1034. (Editor’s Choice)
    DOI: 10.1246/cl.190385
  • Copper-Catalyzed Arylstannylation of Arynes in a Sequence
    H. Tanaka, H. Kuriki, T. Kubo, I. Osaka, H. Yoshida
    Chem. Commun. 2019, 55, 6503–6506.
    DOI: 10.1039/C9CC02738F
  • Anthranilamide-Substituted Borane [H–B(aam)]: Its Stability and Application to Iridium-Catalyzed Stereoselective Hydroboration of Alkynes
    H. Yoshida, M. Kimura, H. Tanaka, Y. Murashige, I. Kageyuki, I. Osaka
    Chem. Commun. 2019, 55, 5420–5422. (Highlighted in Front Cover)
    DOI: 10.1039/C9CC02002K
  • Copper-Catalyzed B(dan)-Installing Allylic Borylation of Allylic Phosphates
    H. Yoshida, Y. Murashige, I. Osaka
    Adv. Synth. Catal. 2019, 361, 2286–2290.
    DOI: 10.1002/adsc.201900342
  • Anthranilamide (aam)-Substituted Arylboranes in Direct Carbon–Carbon Bond-Forming Reactions
    S. Kamio, I. Kageyuki, I. Osaka, H. Yoshida
    Chem. Commun. 2019, 55, 2624–2627.
    DOI: 10.1039/C8CC10252J


  • Anthranilamide (aam)-Substituted Diboron: Palladium-Catalyzed Selective B(aam) Transfer
    S. Kamio, I. Kageyuki, I. Osaka, S. Hatano, M. Abe, H. Yoshida
    Chem. Commun. 2018, 54, 9290–9293.
    DOI: 10.1039/C8CC05645E
  • Preparation of (pin)B–B(dan)
    H. Yoshida, Y. Murashige, I. Osaka
    Org. Synth. 2018, 95, 218–230.
    DOI: 10.15227/orgsyn.095.0218
  • Copper-Catalyzed Borylation of Bromoaryl Triflates with Diborons: Chemoselective Replacement of an Ar–Br Bond
    H. Yoshida, S. Kamio, I. Osaka
    Chem. Lett. 2018, 47, 957–959.
    DOI: 10.1246/cl.180385





  • ホウ素あるいはスズを含む有機典型金属化合物が拓く有機合成
    有機合成化学協会誌 2022, 80, 477–488.
    DOI: 10.5059/yukigoseikyokaishi.80.477


  • Borylation and Stannylation Reactions with Tuning of Lewis Acidity
    H. Yoshida
    Chem. Rec. 2021, 21, 3483–3497.
    DOI: 10.1002/tcr.202100099
  • Recent Advances in Synthetic Transformations with Robust yet Reactive B(dan) Moiety
    J. Li, H. Yoshida
    Heterocycles 2021, 102, 1478–1516.
    DOI: 10.3987/REV-20-949
  • Synthetic Chemistry with Lewis Acidity-Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross-Coupling
    S. Kamio, H. Yoshida
    Adv. Synth. Catal. 2021, 363, 2310–2324. (Selected as VIP)
    DOI: 10.1002/adsc.202001460


  • A Leap forward in Sulfonium Salt and Sulfur Ylide Chemistry
    R. Fan, C. Tan, Y. Liu, Y. Wei, X. Zhao, X. Liu, J. Tan, H. Yoshida
    Chin. Chem. Lett. 2021, 32, 299–312.
    DOI: 10.1016/j.cclet.2020.06.003





  • Product Subclass 6: Silyltin Reagents
    H. Yoshida
    In Science of Synthesis Knowledge Updates, Thieme,2022
    DOI: 10.1055/sos-SD-104-00776
  • Comprehensive Aryne Synthetic Chemistry
    H. Yoshida (Editor)
    Elsevier, 2022, pp. 1–380.
  • Insertion into σ-bonds
    H. Tanaka, H. Yoshida
    In Comprehensive Aryne Synthetic Chemistry, ed. by H. Yoshida, Elsevier, 2022, pp. 57–123.


  • 「アルケン,アルキンのボリル官能基化」「アラインの官能基化」
    吉田 拡人
    有機合成のための新触媒反応101, 有機合成化学協会編,東京化学同人
  • Multicomponent Reactions Involving Arynes and Related Chemistry
    H. Yoshida
    In Modern Aryne Chemistry, ed. by A. T. Biju, Wiley-VCH, 2021, pp. 149–182.
  • N-(Carboxymethyl)-N-Methyl-Glycine
    H. Yoshida
    In e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley, 2021
    DOI: 10.1002/047084289X.rn01228.pub2


  • 1H-Naphtho[1,8-de]-1,3,2-diazaborine, 2,3-Dihydro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
    H. Yoshida
    in e-EROS Encyclopedia of Reagents for Organic Synthesis, Wiley, 2020.
    DOI: 10.1002/047084289X.rn02327
  • Diboron Compounds: Synthesis and Applications
    H. Yoshida
    in Science of Synthesis Reference Library: Advances in Organoboron Chemistry toward Organic Synthesis, ed. by E. Fernández, Thieme, Stuttgart, 2020, pp. 31–82.
    DOI: 10.1055/sos-SD-230-00018